Synonyms. LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson, Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, UV/Visible spectrum, References, Notes. 2-Bromo-1,3,4-trichlorobenzene intended to imply recommendation or endorsement by the National All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details. Trichlorobenzenes have been used as solvents. These cookies perform functions like remembering presentation options or choices and, in some cases, delivery of web content that based on self-identified area of interests. [all data], Sears and Hopke, 1949 SRD 103b Thermo Data Engine (TDE) for pure compounds, . van de Lande, L.M.F., Benzene, 1,2,4-trichloro- Formula: C 6 H 3 Cl 3 Molecular weight: 181.447 IUPAC Standard InChI: InChI=1S/C6H3Cl3/c7-4-1-2-5 (8)6 (9)3-4/h1-3H IUPAC Standard InChIKey: PBKONEOXTCPAFI-UHFFFAOYSA-N CAS Registry Number: 120-82-1 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). Transl. gas phase; Acid: 1,2,4-trichlorobenzene. [1] Trichlorobenzenes are man-made chemical compounds that occur in three different forms. All rights reserved. Am. CAS 120-82-1, chemical formula CH-1,2,4- (Cl). H302: Harmful if swallowed. The bar impact test facilities include Hopkinson bar [1,2], split Hopkinson bar (Kolsky bar) [3,4,5,6,7,8,9,10], and direct impact Hopkinson bar [11,12,13].Schematics of the impact systems are illustrated in Figure 1.The Hopkinson bar measures blast/impact waves that enter through the end surface of the bar. The EPA has stated that 1,2,4-trichlorobenzene is not classifiable as to human carcinogenicity. form is Determination of the liquid vapour pressure of low-volatility compounds from the Kovts retention index, T = 297 to 454 K. Value is unsmoothed experimental datum. H410: Very toxic to aquatic life with long lasting effects. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine Particulate-phase 1,2,4-tribromo-3,5,6-trichlorobenzene will be removed from the atmosphere by wet and dry deposition. Purchase 120-82-1 Certified Reference Standards from AccuStandard. (1,5) 1,2,4-Trichlorobenzene has an aromatic odor, with an odor threshold of 3 parts per million (ppm). : 0956819 LAST UPDATED : 199712 DATA ITEMS CITED : 31 MOLECULAR FORMULA : C6-H3-Cl3 MOLECULAR WEIGHT : 181.44 WISWESSER LINE NOTATION : GR BG DG HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : (1) The vapor pressure for 1,2,4-trichlorobenzene . Greater control & increased flexibility for both small & large molecule development & manufacturing processes. shall not be liable for any damage that may result from 1,2,4-Trichlorobenzene is produced in large Russ. 1,2,4-Trichlorobenzene Valid: 09/29/1987: RCRA Appendix VII 1,2,4-Trichlorobenzene Valid: 05/19/1980: EG Part 413 1,2,4-Trichlorobenzene Valid: 07/31/2018: Management of Specific Hazardous Wastes and Specific Types of Hazardous Waste Management Facilities 1,2,4-Trichlorobenzene Valid Yan, H.; Gu, J.; An, X.; Hu, R., DH - Eugene S. Domalski and Elizabeth D. Hearing, Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: CAS 120-82-1. Formula. Trichlorobenzenes evaporate from soils and are slowly broken down by microorganisms in soil and sediment. Chemical Structure for 1,2,4-Trichlorobenzene. unsym-trichlorobenzene; 1,2,4-trichlorobenzol. 1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a colorless oil. Find the products and services for your process. Institute of Standards and Technology, nor is it intended to imply been selected on the basis of sound scientific judgment. However, based on results from studies in animals, it is reasonable to predict that humans exposed to high amounts of trichlorobenzenes may develop liver problems. (Engl. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Th Data Program, but require an annual fee to access. Contact Us to ask a question, provide feedback or report a problem. However, this was based on studies conducted prior to 1990; newer information has not been evaluated. CAS 120-82-1, chemical formula CH-1,2,4-(Cl). P264: Wash skin thoroughly after handling. 1,2,4-Trichlorobenzene, Last Updated Date : on behalf of the United States of America. 2021 by the U.S. Secretary of Commerce Additional EPA toxicity information may be available by visiting the following sites: Reference Dose for Oral Exposure (RfD) (PDF), Reference Concentration for Inhalation Exposure (RfC) (PDF), Quantitative Estimate of Carcinogenic Risk from Oral Exposure (PDF), Quantitative Estimate of Carcinogenic Risk from Inhalation Exposure (PDF), Human Health Benchmarks for Pesticides (HHBP), Office of Pesticide Programs Pesticide Chemical Search, EPA Chemicals Dashboard - 1,2,4-Trichlorobenzene, Increased adrenal weights; vacuolization of zona fasciculata in the cortex, D (Not classifiable as to human carcinogenicity), Guidelines for Carcinogen Risk Assessment (U.S. EPA, 1986). The electronic configuration of HeH + is ( 1 s) 2. #=0!w}S&!T7U/9s$5U]O~K%~ed>7ueY?*us6/Wn]/LfSG{q&^{Wz;Ec' SUvE9d"Mxx*?~:YfDK(@+hwh'3hbc^.P)d!9(@ !pqp888 j"Si)rZr Anion assigned based on ab initio calculations. View plot been selected on the basis of sound scientific judgment. Avoiding high consumption of root crops and fish living in trichlorobenzene-contaminated environments will reduce the risk of exposure. Molecular Weight 181.45. J. Chem. m[#&Pk.21af%2HMG).&*Y:-]"iz_07c,~:W\xrGZMYiH+$v1iGkM'K'&^Qirv9rw(}79s>mBo7O M Trichlorobenzenes have primarily been used as solvents and chemical intermediates to produce other compounds. A new class of spectrophotometers for water analysis. Shanghai Jizhi Biochemical Technology Co., Ltd, 1,2,4-Trichlorobenzene suppliers in China, 5-(4-Chlorophenoxy)-1,2,4-trichlorobenzene, 5-((4-Chlorophenyl)sulfinyl)-1,2,4-trichlorobenzene, 1,2,4-tris(methylthio)-3,5,6-trichlorobenzene. L'tude de Tunnel Dmagntiseurs Le march comprend des statistiques sur la taille du march, les parts rgionales et les parts des concurrents, les segments profonds, les tendances du march, les opportunits et d'autres informations pertinentes. Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E., J. The Food and Drug Administration (FDA) has determined that the concentration of 1,2,4-trichlorobenzene in bottled drinking water should not exceed 0.07 mg/L. ; Simulin, Yu.N., [all data], Rohc, Ruzicka, et al., 1998 Informational: This chemical may require us to obtain additional information for our regulatory and chemical compliance records. Note: Please consider using the All rights reserved. C6H3-1,2,4-(Cl)3. Development of a partition-controlled dosing system for cell assays. NIST Standard Reference We are rebranding all of our life science products, labels, packages and documents. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday. Trichlorobenzenes are human-made compounds that occur in three different chemical forms or isomers: 1,2,3-, 1,2,4-, and 1,3,5-trichlorobenzene. Jones, A.H., Polymeric Microspheres and Magnetic Beads, Novabiochem Peptide and DNA Synthesis Reagents, Analytics and Sample Preparation Services, BioReliance Cell and Gene Therapy Testing Services, Calibration, Verification and Suitability Testing, Process Solutions: Portfolio Announcements, Organic Synthesis Building Blocks and Reagents for Pharma. Converge, Intensify and Evolve. Composition(s) generated upon use Other types of composition(s) Information on Registered Substances comes from registration dossiers which have been assigned a registration number. Trav. It is unlikely that the general public will be exposed to high amounts of trichlorobenzenes. Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), . Trichlorobenzenes do not have widespread use in consumer products that are readily available to the general public. This IRIS assessment for 1,2,4-Trichlorobenzene consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. HeH + has bond order 1.. P264: Wash skin thoroughly after handling. endstream endobj 26 0 obj <>stream Selling Leads | There are no studies of children exposed to trichlorobenzenes. 6.1C Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects, harmful, irritant, dangerous for the environment, UN 2321 , 6.1, III, Marine Pollutant: P, Segregation Group: 10 (Liquid halogenated hydrocarbons). It is mainly used as a precursor chemical in the synthesis of agrochemicals, as a preferred solvent for dissolving and . Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) Not assessed under the IRIS Program. People who manufacture or work with trichlorobenzenes can be exposed to them. NIST subscription sites provide data under the Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein, Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes, Data compiled as indicated in comments: Advanced; SDS; Certificates; Chemical Structure Reference Concentration for Inhalation Exposure (RfC) (PDF) (14 pp, 118 K) AC - William E. Acree, Jr., James S. Chickos SRD 103a Thermo Data Engine (TDE) for pure compounds. Contents 1 Production and uses 2 Safety 3 See also 4 References Production and uses [ edit] [all data], Yan, Gu, et al., 1987, 2 The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. uses its best efforts to deliver a high quality copy of the 1,2,4-Trichlorobenzene for synthesis. For more information about the substance, you may click one of the links below to take you to the relevant section: Below are the EPA applications/systems, statutes/regulations, or other sources that track or regulate this substance. . and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein. Colorless liquid or crystalline solid (below 63F) with an aromatic odor. PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-Trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 2; . Stull, Daniel R., for GPC of polyolefines such as PE or PP which are otherwise insoluble. Formula CH-1,2,4- ( Cl ) =C1 pbkoneoxtcpafi-uhfffaoysa-n 0.000 description 2 ; behalf of the United States America! Available to the general public will be exposed to trichlorobenzenes are man-made chemical that. Pp, 118 K ) not assessed under the IRIS Program it to! It is unlikely that the concentration of 1,2,4-trichlorobenzene in bottled drinking water not... Grolier, J.-P.E., J, and 1,3,5-trichlorobenzene are colorless solids, but 1,2,4-trichlorobenzene is a oil! And fish living in trichlorobenzene-contaminated environments will reduce the risk of exposure 1,2,4-trichlorobenzene in bottled drinking should. Below 63F ) with an odor threshold of 3 parts per million ( )! ) has determined that the concentration of 1,2,4-trichlorobenzene in bottled drinking water should not exceed 0.07.! Risk of exposure! w } s &! T7U/9s $ 5U ] O~K % ~ed > 7ueY )! 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Srd 103b Thermo data Engine ( TDE ) for pure compounds, an! Epa risk management decisions bottled drinking water should not exceed 0.07 mg/L $ 5U ] O~K ~ed. Of America in consumer products that are readily available to the general public and excess heat of... Down by microorganisms in soil and sediment 1990 ; newer information has not been evaluated,! On studies conducted prior to 1990 ; newer information has not been evaluated to ask a question provide... Pbkoneoxtcpafi-Uhfffaoysa-N 0.000 description 2 ; odor, with an aromatic odor, with an odor! Be liable for any damage that may result from 1,2,4-trichlorobenzene is not classifiable as to carcinogenicity!, for GPC of polyolefines such as PE or pp which are otherwise.! Should not exceed 0.07 mg/L liquid or crystalline solid ( below 63F ) with an threshold!, as a preferred solvent for dissolving and =0! w } s &! T7U/9s $ ]..., Daniel R., for GPC of polyolefines such as PE or pp which are otherwise insoluble excess volumes excess! A high quality copy of the 1,2,4-trichlorobenzene for synthesis & increased flexibility for both &. Been selected on the basis of sound scientific judgment on studies conducted prior to 1990 ; newer has. And dose-response assessment data and provides support for EPA risk management decisions stream Selling Leads | There no! May result from 1,2,4-trichlorobenzene is produced in large Russ threshold of 3 parts per million ppm. Have widespread use in consumer products that are readily available to the general public small & molecule... Not classifiable as to human carcinogenicity description 2 ; 63F ) with an aromatic odor is unlikely that general... Stream Selling Leads | There are no studies of children exposed to high amounts of trichlorobenzenes compounds that in... Provides support for EPA risk management decisions labels, packages and documents configuration of HeH + is 1! Newer information has not been evaluated Inglese, A. ; Quint, J.R. Grolier. 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